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21.
Marina De Nicola Carmela Gambardella Sandro M. Guarino 《Marine pollution bulletin》1992,24(12):619-621
Separate and interactive pollution effects of Cd and Zn on electrophoretically-detected allozyme frequencies of the different genotypes at PGI and PGM loci were studied in Idotea baltica.
Differential survivorship of PGM genotypes was detected in the presence of the single or combined pollutants, while no effect was observed for PGI. Cadmium decreased heterozygosity while zinc or Cd + Zn increased it, suggesting an antithetic action of the two metals and the prevalence of zinc. 相似文献
22.
A detailed experimental mineralogical and geochemical study on hydrothermal alteration processes of volcanic glasses with a different chemical composition and leucites sampled in the Roman Comagmatic Region was carried out. 2g samples of different grain sizes and 50 ml of deionized water or seawater were sealed in bronze Teflon-lined autoclaves and placed in a rotating sample-holder at 200°C. The internal pressure was 16.2 bars. At arbitrary intervals, the pressure vessel was quenched to room temperature and both solids and solutions were separated by filtration. The solids were used to identify possible alteration products by means of X-ray powder diffraction, SEM and microprobe analyses. In all deionized water systems the contact solution reached pH basic values, but in the various systems the consumption of H+ ions occurred in different ways. This is probably linked to different concentrations of released cations. In seawater systems, however, pH values initially fell sharply but subsequently increased slightly. After 2 days, cation concentrations were clearly buffered by reaction products in all solutions. These were mainly zeolites and clay minerals. The following crystallization sequences in all glass/deionized water experiments were observed: the first reaction product was represented by phillipsite, followed by analcime and illite in the alkali-trachytic run; chabasite and analcime in the phonolitic-tephritic run; analcime and finally feldspar in shoshonitic and trachytic runs. Phillipsite and smectite crystallized together only in the basaltic run. In leucite/deionized water systems, however, the first reaction phase was illite, followed by analcime and then phillipsite. The reaction products in glass/seawater systems were smectite and anydrite. The chemical composition of synthetic zeolites was clearly controlled by the chemistry of initial glasses. These synthetic zeolites are like the natural ones in volcaniclastic products from central and southern Italy. This suggests that extensive zeolitization processes of these volcaniclastic rocks may occur through interaction of volcanic glasses with fluids at a very low salinity and a temperature close to 200°C. 相似文献
23.
Carmela Freda Mario Gaeta Valeria Misiti Silvio Mollo Daniela Dolfi Piergiorgio Scarlato 《Lithos》2008,101(3-4):397-415
The Alban Hills ultrapotassic volcanic district is one of the main districts emplaced during Quaternary time along the Tyrrhenian margin of Italy. Alban Hills lava flows and scoria clasts are made up essentially of clinopyroxenes and leucites and their chemical composition is mostly K-foiditic. Differentiated products (MgO < 3 wt.%) are characterised by low SiO2 concentration (< 50 wt.%) and geochemical features indicate that this unique differentiation trend is driven by crystal fractionation plus carbonate crust interaction. Notably, the Alban Hills Volcanic District was emplaced into thick limestone units. With the aim of constraining the magmatic differentiation, we performed experiments on the Alban Hills parental composition (plagioclase-free phono-tephrite) under anhydrous, hydrous, and hydrous-carbonated conditions. Experiments were carried out at 1 atm, 0.5 GPa and 1 GPa, temperatures ranging from 1050 to 1300 °C, and H2O and CaCO3 in the starting material up to 2 and 7 wt.%, respectively. The experiments performed at 0.5 GPa are the most representative of the Alban Hills plumbing system. Clinopyroxene and leucite are the main phases occurring under all the investigated conditions and the liquidus phases. Nevertheless, our experimental results demonstrate that the occurrence of CaCO3 in the starting material strongly affects phase relations. Experiments performed under hydrous conditions crystallize magnetite and phlogopite at relatively high temperature. This early crystallization drives the glass composition towards a silica enrichment, resulting in a differentiation trend moving from phono-tephritic (Alban Hills parental composition) to phonolitic compositions. This is in contrast with micro-textural evidence showing late crystallization of magnetite and phlogopite in the natural products and with the composition of the juvenile products. On the contrary, in the CaCO3-bearing experiments (i.e., simulating magma–carbonate interaction) the magnetite and phlogopite stability fields are strongly reduced. As a consequence, the melt differentiation is mainly controlled by the cotectic crystallization of clinopyroxene and leucite, resulting in a differentiation trend moving towards K-foiditic compositions. These experimental results are in agreement with micro-textural features and chemical compositions of Alban Hills natural products and with the magmatic differentiation model inferred by geochemical data. Magma–carbonate interaction is not a rare process and its occurrence has been demonstrated for different plumbing systems. However, the uniqueness of the Alban Hills liquid line of descent suggests that the efficacy of the carbonate contamination process is controlled by different factors, the dynamics of the plumbing system being one of the most important. 相似文献
24.
Roghieh?DorooziEmail author Carmela?Vaccaro Fariborz?Masoudi 《Arabian Journal of Geosciences》2016,9(15):665
The Kamarbon alkaline gabbroic intrusion crops out in Central Alborz, north Iran, along the northern margin of the Alpine-Himalayan belt. The gabbroic intrusion includes theralites at margins which replace with teschenites toward the center. In teschenitic rocks, the main minerals are diopside, clinopyroxene, and rhönite. In this research, the occurrence of rhönite is reported in Kamarbon teschenitic gabbros, and also its mineralogical properties, paragenesis, and source magma are investigated. Based on whole rock and microprobe analysis data, we try to clarify the formation of Kamarbon gabbro and the crystallization condition of rhönite. In teschenitic gabbros, rhönite reveals the composition (Na, Ca)1.97(Ti, VIAl, Fe+3, Fe+2, Mn, Mg)5.99(Si, IVAl)6.02O20. On the basis of petrographical observations and mineral chemistry, we suggest that the teschenites were formed in distinctive lower pressures and temperatures than theralites, below 1.9 kbar and 1075 °C. Rhönite was crystallized (at the mentioned P-T condition) as a primary phase, in the late stage of crystallization at shallow depth corresponding with 6–10 km, in teschenites. Important factors of the rhönite crystallization in undersaturated magmas can be regardarded as Al and Ti enrichment and Si depletion; the same enrichment and depletion are also observed in the associated clinopyroxenes. 相似文献
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26.
We calculate the event rates induced by a 51Cr νe source and by a 90Sr---90Y
source in BOREXINO through elastic scattering on electrons, assuming a nonzero neutrino magnetic moment μν. We consider a source activity of about 2 MCi and estimate the solar ν (“source-off”) background for various oscillation scenarios. It is shown that values of μν as low as 0.5 × 10−10μB ( 0.2 × 10−10μB) can be proved with the 51Cr source (90Sr source) in about 100 days of data taking. 相似文献
27.
Alessandro Mondanaro Mirko Di Febbraro Marina Melchionna Francesco Carotenuto Silvia Castiglione Carmela Serio Simone Danisi Lorenzo Rook Jose Alexandre F. Diniz‐Filho Pasquale Raia 《Boreas: An International Journal of Quaternary Research》2019,48(3):605-615
Cave bears (Ursus spelaeus) are an iconic component of the European late Quaternary Ice Age megafauna. Recent demographic analyses based on cave bear mtDNA sequences and refined radiocarbon dating indicate that cave bear population size and genetic diversity started to decline some 50 kilo years ago (kya). Hence, neither the coldest phase of the last glaciation (started some 24 kya), nor the colonization of Europe by Palaeolithic hunters (started some 45 kya) coincides with the beginning of population decline. Here, we reconstructed cave bear climatic niche evolution through time. Then, we performed spatially explicit population viability analyses to assess cave bear demographics through time in response to climatic changes, human effects on bear survival and their combination. We found that climate change was responsible for a 10‐fold decrease in cave bear population size after 40 kya. However, climate change on its own could not explain U. spelaeus extinction at 24 kya. Additional negative effects consistent with human population expansion are required to explain both U. spelaeus' retreat from eastern Europe since 40 kya and its final extinction. 相似文献
28.
Myriam Andrea Rada Torres Vincenzo Costanzo-Álvarez Milagrosa Aldana Nery Suárez Corina Campos Maria Magdalena Mackowiak-Antczak María Carmela Brandt 《Studia Geophysica et Geodaetica》2011,55(4):717-736
Rock magnetic, petrographic and dielectric analyses were carried out, in a number of archeological ceramic potsherds, in order
to characterize the different manufacturing techniques used by Prehistoric Venezuelan Amerindian potters. Samples were excavated
in 7 Venezuelan islands and ascribed to distinct cultural groups on purely stylistic grounds (i.e. Valencioide, Ocumaroide,
Dabajuroide and Unknown). Mean coercivity values were determined through a direct signal analyses (DSA) applied to isothermal
remanent magnetization (IRM) acquisition curves. Logarithmic plots of these mean coercivities are the best quantitative means
to classify diverse ceramics. The mean coercivity values seem to group the samples according to the manufacturing development.
These values also seem to discriminate the samples provenance, indeed, this plot displays a good grouping of data for samples
presumably manufactured by the same culture but excavated at different locations. Thermomagnetic cycles supply helpful information
about original ceramic firing conditions. The irreversibility parameter (IP) for thermomagnetic curves (heating and cooling),
serves as an indicator of the amount of organic matter burnt during original pottery firing. The IP for a number of pottery
samples from Venezuelan islands and mainland, with ages ranging between 300 BC to 1500 AD, might suggest a possible increasing
trend in time towards the complete reversibility line of IP = 0. Most samples, independently of age and cultural group, have
IP values that suggest that most open fires, used by primitive Venezuelan Amerindian potters, had enough ventilation and oxidizing
atmospheres. A scatter plot of maximum current depolarization temperatures versus natural remanent magnetization (NRM) suggests
a complex non-linear relationship between these two parameters most likely due to the fact that both, dielectric and rock
magnetic data, are linked to pore-related features. 相似文献
29.
Rosalda Punturo Carmelisa D’Antone Salvatore Pepi Carmela Vaccaro 《Environmental Earth Sciences》2018,77(24):801
Vitis vinifera L. vineyards grown on carbonate soil (Hyblean Plateau, SE Sicily) have been characterized in terms of rare earth elements (REEs) distribution. Results highlighted that the absorption of REEs by plants depends on the composition of the underlying soil, which in this case derives from limestone parent rock, allowing us to recognize the area of origin. Indeed, even slight differences in REEs content in soils may affect the absorption pattern of each grapevine cultivar. Importantly, the various parts of the plants showed differences in REEs absorption; such REEs fractionation is particularly evident in the leaf and juice samples. In general, the uptake and concentrations of REEs in plant tissues may be related to many factors such as geographical, climatic and lithological features. This is also pointed out by the statistical investigation, which took into account either the grapevine variety or each part of the plant. By taking into consideration both the grape variety and the type of soil, the present “multi-elemental” approach aims to provide a useful geochemical tool for assessing the geographical origin of the production area of wine. 相似文献
30.
Robust date for the Bronze Age Avellino eruption (Somma-Vesuvius): 3945 ± 10 calBP (1995 ± 10 calBC)
Jan Sevink Manfred J. van Bergen Johannes van der Plicht Hendrik Feiken Carmela Anastasia Annika Huizinga 《Quaternary Science Reviews》2011,30(9-10):1035-1046
We found Bronze Age lake sediments from the Agro Pontino graben (Central Italy) to contain a thin (2–3 cm) continuous tephra layer composed of lithics, crystals and minor volcanic glass. Tephrochronological and compositional constraints strongly suggest that this layer represents the Avellino pumice eruption, which has also been identified in Central Italian lake cores. Its provenance is corroborated by electron-microprobe analyses performed on juvenile pumice grains, showing that the tephra layer is probably the distal equivalent of the EU2 event of the Avellino eruption. We used multiple 14C age estimations of two lacustrine sequences with intercalated tephra layer, from the western border zone (Migliara 44.5) and the centre of the former lake (Campo Inferiore), for in tandem dating of this eruption, employing the OxCal code, which yielded a robust age of 3945 ± 10 calBP (1995 ± 10 calBC). To date, this is the only study providing both a terminus post and terminus ante quem of this precision, also demonstrating the advantage of dating distal tephra layers in a clear stratigraphic context over proximal deposits in sequences with major stratigraphic hiatuses. Our new results underscore the importance of the Avellino tephra layer as a precise time marker for studies on the Early Bronze Age of Central Italy. 相似文献